Barrymore is CoverGirl’s newest model and spokeswoman, joining a stable of famous faces that includes her former idols and, more recently, Queen Latifah, Molly Sims and Rihanna.

    Her selection by the Procter & Gamble Co. beauty brand was to be announced Wednesday at a news conference in Los Angeles.

    The 32-year-old ”Charlie’s Angels” actress is also a co-creator of the ads, and before any wardrobe or beauty decisions were made at Monday’s print shoot, Barrymore said ...